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• W2938668718 endingPage "7199" @default.
• W2938668718 startingPage "7194" @default.
• W2938668718 abstract "Oxygenation reaction of cyclohexene was studied under the presence of a fourfold UO22+ complex with cyclohexyldiphenylphosphine oxide, [UO2(OPCyPh2)4]2+, and blue light irradiation at 436 nm in acetonitrile. As a result, 1,6-hexanedial, cyclohexene oxide, 2-cyclohexen-1-one, and 2-cyclohexen-1-ol were photocatalytically generated as oxygenated products with turnover frequency = 6.7 h–1. In contrast, dimerization of cyclohexene was observed under Ar atmosphere. This implies that a hydrogen atom at the allyl position is abstracted by photoexcited *[UO2(OPCyPh2)4]2+ to give a cyclohexene radical and a U(V) intermediate [UVO2(OPCyPh2)4]+, being well supported by the density functional theory calculation. Under an O2 atmosphere, the former reacts with dissolved O2 to give 2-cyclohexen-1-one and 2-cyclohexen-1-ol. Dissolved O2 would be activated by the U(V) intermediate to afford O22– in the end, which drives oxygenation of the C═C bond of unreacted cyclohexene." @default.
• W2938668718 created "2019-04-25" @default.
• W2938668718 creator A5010319342 @default.
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• W2938668718 date "2019-04-19" @default.
• W2938668718 modified "2023-10-03" @default.
• W2938668718 title "Photocatalytic Oxygenation of Cyclohexene Initiated by Excitation of [UO₂(OPCyPh₂)₄]²⁺ under Visible Light" @default.
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• W2938668718 doi "https://doi.org/10.1021/acsomega.9b00635" @default.
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