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- W2938794811 abstract "Two mercury selenite compounds HgM(SeO3)2(H2O)2 (M = Co, Ni) are synthesized using a conventional hydrothermal method. Both compounds crystallize in the monoclinic structure with a C2/c space group, and equivalent Co2+ or Ni2+ ions exhibit a stacked triangular lattice. Magnetic measurements suggest different magnetic properties between these two isostructural compounds, in which HgCo(SeO3)2(H2O)2 undergoes a canted antiferromagnetic order below TN = 7.6 K, while HgNi(SeO3)2(H2O)2 exhibits a collinear antiferromagnetic order below TN = 9.0 K. When applying a magnetic field, two successive magnetic transitions are observed at Bc1 ∼ 1 T and Bc2 ∼ 3.6 T in HgCo(SeO3)2(H2O)2, whereas only one field-induced transition is detected around 3.1 T in HgNi(SeO3)2(H2O)2." @default.
- W2938794811 created "2019-04-25" @default.
- W2938794811 creator A5010534882 @default.
- W2938794811 creator A5025961190 @default.
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- W2938794811 date "2019-04-18" @default.
- W2938794811 modified "2023-10-16" @default.
- W2938794811 title "Synthesis, Structure, and Magnetic Properties of Two Mercury Selenite Antiferromagnets HgM(SeO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub> (M = Co, Ni)" @default.
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- W2938794811 doi "https://doi.org/10.1021/acs.inorgchem.9b00008" @default.
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