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• W2938902446 abstract "We have investigated the surface effect of colloidally prepared CdSe nanocrystals (NCs) with the size range of 23-40 Å on their structural properties by changing the organic capping ligands. The TOPO/HDA-passivated NCs reveal a size-dependent behavior involving an elongated axial bond R (1) of an atomic tetrahedron and a shrunken equatorial bonds R (2) . After treatment of the NCs with pyridine, the bond length R (1) decreases significantly whereas R (2) remains unchanged relative to the TOPO/HDA-passivated NCs, suggesting that a tensile stress along the [001] direction is contributed from the surface modification. In addition, we find that the expansion ratio of the pyridine-treated NCs along the c axis depends strongly on the density of stacking faults, which provides an evidence for the relaxation of atomic positions near the interface of stacking faults." @default.
• W2938902446 created "2019-04-25" @default.
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• W2938902446 date "2019-04-01" @default.
• W2938902446 modified "2023-09-28" @default.
• W2938902446 title "Dependence of Tetrahedral Bond Lengths on the Surface Passivation and Stacking-Fault Density of CdSe Nanocrystals" @default.
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• W2938902446 doi "https://doi.org/10.4028/www.scientific.net/jnanor.57.58" @default.
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