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- W2938938077 abstract "A novel phosphate, sodium zinc aluminium bis(phosphate), NaZnAl(PO 4 ) 2 , was obtained under mild-temperature hydrothermal conditions at 553 K. The crystal structure has been studied using single-crystal X-ray experimental data. The pseudo-hexagonal phase NaZnAl(PO 4 ) 2 crystallizes in the monoclinic space group P 2 1 / c . Its unique crystal structure is based on a three-dimensional (3D) framework built by Zn-, Al- and P-centred tetrahedra sharing vertices. Channels parallel to the [101] and [overline{1}01] directions are limited by six- and eight-membered windows, and incorporate Na atoms. The new compound is discussed as a member of the morphotropic series AMM ′PO 4 , where A = Na, K, Rb or NH 4 , M = Cu, Ni, Co, Fe, Zn or Mg and M ′ = Fe, Al or Ga. The title compound is the first Na representative within the series and is characterized by a 3D architecture of tetrahedra populated in an ordered manner by Zn 2+ , Al 3+ and P 5+ ions." @default.
- W2938938077 created "2019-04-25" @default.
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- W2938938077 date "2019-04-08" @default.
- W2938938077 modified "2023-10-03" @default.
- W2938938077 title "The rich crystal chemistry of the<i>AMM</i>′(PO<sub>4</sub>)<sub>2</sub>morphotropic series: NaZnAl(PO<sub>4</sub>)<sub>2</sub>, the first Na representative with a new structure type" @default.
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- W2938938077 doi "https://doi.org/10.1107/s2053229619004327" @default.
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