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• W2939841605 endingPage "16423" @default.
• W2939841605 startingPage "16411" @default.
• W2939841605 abstract "The unoccupied electronic structures of three closed-shell, highly popular organoiron complexes ([Fe(CO)5], [(η5-C5H5)Fe(CO)(μ-CO)]2, and [(η5-C5H5)2Fe]; 0, I, and II, respectively) have been investigated both experimentally and theoretically by combining original gas-phase X-ray absorption spectroscopy (XAS) outcomes recorded at the C and O K-edge with results of scalar relativistic time-dependent density functional calculations carried out within the zeroth order regular approximation. Experimental evidence herein discussed complement the Fe L2,3-edges XAS ones we recently recorded, modeled, and assigned for the same complexes (Carlotto et al. Inorg. Chem. 2019, 58, 5844). The first-principle simulation of the C and O K-edge features allowed us to univocally identify the electronic states associated to the ligand-to-metal charge transfer (LMCT) transitions both in I and in II. At variance to that, LMCT transitions with sizable oscillator strengths do not play any role in determining neither the C nor the O K-edge spectral pattern of 0. The higher π-acceptor capability of the CO ligand, regardless of its terminal or bridging coordination, with respect to [(η5-C5H5)]- is herein ultimately confirmed." @default.
• W2939841605 created "2019-04-25" @default.
• W2939841605 creator A5007575645 @default.
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• W2939841605 creator A5043605720 @default.
• W2939841605 creator A5051740488 @default.
• W2939841605 creator A5058865471 @default.
• W2939841605 date "2019-11-22" @default.
• W2939841605 modified "2023-09-25" @default.
• W2939841605 title "Comparative Experimental and Theoretical Study of the C and O K-Edge X-ray Absorption Spectroscopy in Three Highly Popular, Low Spin Organoiron Complexes: [Fe(CO)₅], [(η⁵-C₅H₅)Fe(CO)(μ-CO)]₂, and [(η⁵-C₅H₅)₂Fe]" @default.
• W2939841605 cites W1650728208 @default.
• W2939841605 cites W1909826434 @default.
• W2939841605 cites W1963951169 @default.
• W2939841605 cites W1964921738 @default.
• W2939841605 cites W1965596683 @default.
• W2939841605 cites W1969876805 @default.
• W2939841605 cites W1972314474 @default.
• W2939841605 cites W1974781730 @default.
• W2939841605 cites W1980774210 @default.
• W2939841605 cites W1983852130 @default.
• W2939841605 cites W1984701855 @default.
• W2939841605 cites W1996575787 @default.
• W2939841605 cites W1996839819 @default.
• W2939841605 cites W2000309069 @default.
• W2939841605 cites W2001577841 @default.
• W2939841605 cites W2003409499 @default.
• W2939841605 cites W2006636346 @default.
• W2939841605 cites W2008423326 @default.
• W2939841605 cites W2009322333 @default.
• W2939841605 cites W2010651235 @default.
• W2939841605 cites W2017786850 @default.
• W2939841605 cites W2019752459 @default.
• W2939841605 cites W2021625936 @default.
• W2939841605 cites W2022235310 @default.
• W2939841605 cites W2025390841 @default.
• W2939841605 cites W2031903596 @default.
• W2939841605 cites W2033273407 @default.
• W2939841605 cites W2034979775 @default.
• W2939841605 cites W2048399437 @default.
• W2939841605 cites W2049095908 @default.
• W2939841605 cites W2057191096 @default.
• W2939841605 cites W2060565841 @default.
• W2939841605 cites W2063662539 @default.
• W2939841605 cites W2064821379 @default.
• W2939841605 cites W2069478064 @default.
• W2939841605 cites W2072714349 @default.
• W2939841605 cites W2072880656 @default.
• W2939841605 cites W2084229322 @default.
• W2939841605 cites W2085230192 @default.
• W2939841605 cites W2090638789 @default.
• W2939841605 cites W2091604189 @default.
• W2939841605 cites W2095374362 @default.
• W2939841605 cites W2108446403 @default.
• W2939841605 cites W2113084681 @default.
• W2939841605 cites W2116373706 @default.
• W2939841605 cites W2122818112 @default.
• W2939841605 cites W2124435248 @default.
• W2939841605 cites W2133916062 @default.
• W2939841605 cites W2150195378 @default.
• W2939841605 cites W2150345533 @default.
• W2939841605 cites W2150697053 @default.
• W2939841605 cites W2154153665 @default.
• W2939841605 cites W2156257115 @default.
• W2939841605 cites W2158691879 @default.
• W2939841605 cites W2166198169 @default.
• W2939841605 cites W2171710937 @default.
• W2939841605 cites W2171962907 @default.
• W2939841605 cites W2189977243 @default.
• W2939841605 cites W2344432887 @default.
• W2939841605 cites W2479651558 @default.
• W2939841605 cites W2519970491 @default.
• W2939841605 cites W2587383222 @default.
• W2939841605 cites W261429815 @default.
• W2939841605 cites W2734624985 @default.
• W2939841605 cites W2737134576 @default.
• W2939841605 cites W2746249669 @default.
• W2939841605 cites W2787107754 @default.
• W2939841605 cites W289896929 @default.
• W2939841605 cites W2967097838 @default.
• W2939841605 cites W3021204293 @default.
• W2939841605 cites W3144642009 @default.
• W2939841605 cites W4233722703 @default.
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• W2939841605 doi "https://doi.org/10.1021/acs.inorgchem.9b02107" @default.
• W2939841605 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31756086" @default.
• W2939841605 hasPublicationYear "2019" @default.
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