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- W2940116701 abstract "[Ni(CO) 2 (dppf)] [ 1 ] {dppf = 1,1′‐bis(diphenylphosphino)ferrocene} was made by reductive carbonylation of [NiCl 2 (dppf)] with [Fe(CO) 5 ], similar to our recent report in Organometallics , 2019 , 38 , 586–592. Complex [ 1 ] showed two oxidation waves in the cyclic voltammogram. UV/Vis‐NIR spectroelectrochemistry (SEC) and IR SEC at –30 °C as well as computational support by means of DFT was used to assign the oxidation state of both metal atoms after oxidation. The monocation [ 1 ] + showed a strong NIR absorption band which was described as an IVCT [Ni I →Fe II ] and inverse IVCT (iIVCT) or hole transfer [Fe II →Ni I ] based on time dependence DFT (TD‐DFT). The IR SEC spectrum of [ 1 ] + showed multiple bands associated with two similar configurations, one which had the spin delocalized over both metal atoms and a second configuration where the spin is primarily Ni localized. The second oxidation to [ 1 ] 2+ occurred at the Ni atom and resulted in release of a CO ligand followed by the formation of dimeric complex determined by low temperature IR SEC." @default.
- W2940116701 created "2019-04-25" @default.
- W2940116701 creator A5034978213 @default.
- W2940116701 creator A5036833506 @default.
- W2940116701 date "2019-05-09" @default.
- W2940116701 modified "2023-10-16" @default.
- W2940116701 title "Anodic Mechanism of 1,1′-Bis(diphenylphosphino)ferrocenedicarbonylnickel Determined by Low-Temperature Spectroelectrochemistry" @default.
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- W2940116701 doi "https://doi.org/10.1002/ejic.201900150" @default.
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