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- W2940167620 abstract "An operationally simple method has been developed for the preparation of N ‐unsubstituted benzotriazoles by diazotization and intramolecular cyclization of a wide range of 1,2‐aryldiamines under mild conditions, using a polymer‐supported nitrite reagent and p ‐tosic acid. The functional group tolerance of this approach was further demonstrated with effective activation and cyclization of N ‐alkyl, ‐aryl, and ‐acyl ortho ‐aminoanilines leading to the synthesis of N 1 ‐substituted benzotriazoles. The synthetic utility of this one‐pot heterocyclization process was exemplified with the preparation of a number of biologically and medicinally important benzotriazole scaffolds, including an α‐amino acid analogue." @default.
- W2940167620 created "2019-04-25" @default.
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- W2940167620 date "2019-05-09" @default.
- W2940167620 modified "2023-10-18" @default.
- W2940167620 title "Synthesis of Structurally Diverse Benzotriazoles via Rapid Diazotization and Intramolecular Cyclization of 1,2‐Aryldiamines" @default.
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- W2940167620 doi "https://doi.org/10.1002/ejoc.201900463" @default.
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