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• W2940195552 abstract "Crystals of the quaternary compounds α-Lu(Al 1-x T x )B 4 (T = Fe, Cr) (YCrB 4 -type, orthorhombic, Pbam), obtained from the nominal composition of Lu(Al 1-x T x )B 3 , were grown by using Al flux mixed with T metal at 1773 K for 5 h under an Ar atmosphere. The maximum dimensions and morphology of the crystals obtained were about 0.7 mm × 0.5 mm for flake-type crystals of Lu(Al 1-x Cr x )B 4 and about 5.2 mm × 0.2 mm for prism crystals of Lu(Al 1-x Fe x )B 4 . The lattice constants determination and chemical analyses of Lu(Al 1-x T x )B 4 (T = Fe, Cr) compounds were carried out for Fe 0.5 - 10.0 at% and Cr 0.5 - 1.0 at%. The lattice constants and the unit lattice volume in Lu(Al 1-x T x )B 4 crystals decreased with increase of the concentration of Fe or Cr. The values of micro-Vickers hardness of Lu(Al 1-x Fe x )B 4 (x = 0.005 - 0.030) and Lu(Al 1-x Cr x )B 4 (x = 0.005 - 0.010) samples are in the ranges of 16(2) - 20(3) GPa and 13(2) - 16(3) GPa, respectively. The hardness values showed a little increase as the solid solution of Fe or Cr was realized in Lu(Al 1-x T x )B 4 , possibly because of distortion to the crystal structure. The magnetic susceptibility of as-grown Lu(Al 0.995 Fe 0.005 )B 4 crystals for example, exhibited diamagnetic behavior with a small ferromagnetic component." @default.
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• W2940195552 date "2019-04-01" @default.
• W2940195552 modified "2023-10-05" @default.
• W2940195552 title "Crystal Growth and Physical Properties of Lu(Al_1-x<i>T</i>_x)B₄ (<i>T</i> = Fe, Cr) by Al-Self Flux" @default.
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• W2940195552 doi "https://doi.org/10.4028/www.scientific.net/ssp.289.120" @default.
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