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- W2940217263 endingPage "7604" @default.
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- W2940217263 abstract "Unusual binding properties, enabling the stabilization of elusive species, and beneficial properties for homogeneous catalysts have been predicted and demonstrated for ligand-stabilized main group fragments, such as carbodiphosphoranes and -carbenes. However, the quantification and comparison of their binding properties by experimental means still represent major challenges. In this article, we describe a series of iridium(III) pincer complexes of the type [(PEP)IrCl(CO)(H)]q enabling the quantification of the donor strength of the central donor group E (q = 0, +1, +2). Our investigations show that phosphine-stabilized boron(I) and carbon(0) compounds are exceptionally strong neutral donor groups in comparison to common spectator ligands in homogeneous catalysis such as carbenes and phosphines. Our experimental and computational results for the first time allow and justify the comparison of the donor strength of cationic, neutral, and anionic ligands. On the basis of quantum chemical investigations, we further demonstrate that the heavier homologues of phosphine-stabilized borylenes and carbon(0) compounds exhibit slightly diminished donor properties." @default.
- W2940217263 created "2019-04-25" @default.
- W2940217263 creator A5072066732 @default.
- W2940217263 creator A5073803429 @default.
- W2940217263 creator A5078076793 @default.
- W2940217263 creator A5081613061 @default.
- W2940217263 creator A5071588579 @default.
- W2940217263 date "2019-04-17" @default.
- W2940217263 modified "2023-10-17" @default.
- W2940217263 title "Quantifying the Donor Strength of Ligand-Stabilized Main Group Fragments" @default.
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