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- W2940344570 abstract "A novel metal-free synthesis of 3,3-disubstituted benzofuran-2-(3H)-ones through reacting α-aryl-α-diazoacetates with triarylboranes is presented. Initially, triarylboranes were successfully investigated in α-arylations of α-diazoacetates, however in the presence of a heteroatom in the ortho position, the boron enolate intermediate undergoes an intramolecular rearrangement to form a quaternary center. The intermediate cyclizes to afford valuable 3,3-disubstituted benzofuranones in good yields." @default.
- W2940344570 created "2019-04-25" @default.
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- W2940344570 date "2019-06-03" @default.
- W2940344570 modified "2023-10-17" @default.
- W2940344570 title "Metal‐Free Tandem Rearrangement/Lactonization: Access to 3,3‐Disubstituted Benzofuran‐2‐(3 <i>H</i> )‐ones" @default.
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- W2940344570 doi "https://doi.org/10.1002/anie.201902985" @default.
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