Matches in SemOpenAlex for { <https://semopenalex.org/work/W2940419777> ?p ?o ?g. }
- W2940419777 endingPage "164" @default.
- W2940419777 startingPage "154" @default.
- W2940419777 abstract "Abstract The early stages of soot formation, namely inception and growth, are highly debated and central to many ongoing studies in combustion research. Here, we provide new insights into these processes from studying different soot samples by atomic force microscopy (AFM). Soot has been extracted from a slightly sooting, premixed ethylene/air flame both at the onset of the nucleation process, where the particle size is of the order of 2–4 nm, and at the initial stage of particle growth, where slightly larger particles are present. Subsequently, the molecular constituents from both stages of soot formation were investigated using high-resolution AFM with CO-functionalized tips. In addition, we studied a model compound to confirm the atomic contrast and AFM-based unambiguous identification of aliphatic pentagonal rings, which were frequently observed on the periphery of the aromatic soot molecules. We show that the removal of hydrogen from such moieties could be a pathway to resonantly stabilized π-radicals, which were detected in both investigated stages of the soot formation process. Such π-radicals could be highly important in particle nucleation, as they provide a rational explanation for the binding forces among aromatic molecules." @default.
- W2940419777 created "2019-04-25" @default.
- W2940419777 creator A5008948855 @default.
- W2940419777 creator A5012890301 @default.
- W2940419777 creator A5026620470 @default.
- W2940419777 creator A5056918206 @default.
- W2940419777 creator A5068716800 @default.
- W2940419777 creator A5080939754 @default.
- W2940419777 date "2019-07-01" @default.
- W2940419777 modified "2023-10-12" @default.
- W2940419777 title "On the early stages of soot formation: Molecular structure elucidation by high-resolution atomic force microscopy" @default.
- W2940419777 cites W1164759160 @default.
- W2940419777 cites W1907369419 @default.
- W2940419777 cites W1938737395 @default.
- W2940419777 cites W1964084591 @default.
- W2940419777 cites W1964565139 @default.
- W2940419777 cites W1967445304 @default.
- W2940419777 cites W1968523272 @default.
- W2940419777 cites W1969699263 @default.
- W2940419777 cites W1971433810 @default.
- W2940419777 cites W1974705036 @default.
- W2940419777 cites W1975639388 @default.
- W2940419777 cites W1980637262 @default.
- W2940419777 cites W1986055204 @default.
- W2940419777 cites W1990842728 @default.
- W2940419777 cites W1993626332 @default.
- W2940419777 cites W1995551012 @default.
- W2940419777 cites W2004426365 @default.
- W2940419777 cites W2005605656 @default.
- W2940419777 cites W2007702024 @default.
- W2940419777 cites W2010799106 @default.
- W2940419777 cites W2013783548 @default.
- W2940419777 cites W2017547201 @default.
- W2940419777 cites W2017698070 @default.
- W2940419777 cites W2024747980 @default.
- W2940419777 cites W2027447425 @default.
- W2940419777 cites W2033298286 @default.
- W2940419777 cites W2037504287 @default.
- W2940419777 cites W2045747043 @default.
- W2940419777 cites W2049694692 @default.
- W2940419777 cites W2051001465 @default.
- W2940419777 cites W2051148391 @default.
- W2940419777 cites W2054961768 @default.
- W2940419777 cites W2055266359 @default.
- W2940419777 cites W2056551052 @default.
- W2940419777 cites W2060521253 @default.
- W2940419777 cites W2061099521 @default.
- W2940419777 cites W2064848622 @default.
- W2940419777 cites W2065283211 @default.
- W2940419777 cites W2071376591 @default.
- W2940419777 cites W2073725433 @default.
- W2940419777 cites W2075230606 @default.
- W2940419777 cites W2075715275 @default.
- W2940419777 cites W2077395572 @default.
- W2940419777 cites W2079037945 @default.
- W2940419777 cites W2081144981 @default.
- W2940419777 cites W2081993578 @default.
- W2940419777 cites W2085164220 @default.
- W2940419777 cites W2086959137 @default.
- W2940419777 cites W2093811408 @default.
- W2940419777 cites W2101725229 @default.
- W2940419777 cites W2115123250 @default.
- W2940419777 cites W2121706795 @default.
- W2940419777 cites W2137169911 @default.
- W2940419777 cites W2156902602 @default.
- W2940419777 cites W2191247980 @default.
- W2940419777 cites W2199686530 @default.
- W2940419777 cites W2316926861 @default.
- W2940419777 cites W2338258327 @default.
- W2940419777 cites W2471340433 @default.
- W2940419777 cites W2531192430 @default.
- W2940419777 cites W2554188511 @default.
- W2940419777 cites W2562471952 @default.
- W2940419777 cites W2576500360 @default.
- W2940419777 cites W2606526100 @default.
- W2940419777 cites W2614765143 @default.
- W2940419777 cites W2621696159 @default.
- W2940419777 cites W2762510040 @default.
- W2940419777 cites W2809141617 @default.
- W2940419777 cites W2809253383 @default.
- W2940419777 cites W2810535486 @default.
- W2940419777 cites W2892060029 @default.
- W2940419777 cites W4243577461 @default.
- W2940419777 doi "https://doi.org/10.1016/j.combustflame.2019.03.042" @default.
- W2940419777 hasPublicationYear "2019" @default.
- W2940419777 type Work @default.
- W2940419777 sameAs 2940419777 @default.
- W2940419777 citedByCount "127" @default.
- W2940419777 countsByYear W29404197772019 @default.
- W2940419777 countsByYear W29404197772020 @default.
- W2940419777 countsByYear W29404197772021 @default.
- W2940419777 countsByYear W29404197772022 @default.
- W2940419777 countsByYear W29404197772023 @default.
- W2940419777 crossrefType "journal-article" @default.
- W2940419777 hasAuthorship W2940419777A5008948855 @default.
- W2940419777 hasAuthorship W2940419777A5012890301 @default.
- W2940419777 hasAuthorship W2940419777A5026620470 @default.
- W2940419777 hasAuthorship W2940419777A5056918206 @default.