FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2941001873> ?p ?o ?g. }

• W2941001873 endingPage "197" @default.
• W2941001873 startingPage "191" @default.
• W2941001873 abstract "Metal-organic frameworks (MOFs) are porous 3-dimensional crystalline structures that have shown promise for a variety of applications including adsorption, catalysis, and sensing. Modern warfare has placed chemical warfare agent (CWA) destruction at the forefront of chemical applications for MOFs. However, experiments involving CWAs can only be performed by a small number of highly trained individuals as they are extremely dangerous and available only to certain laboratories. As such, it is imperative that suitable chemical simulants and reaction conditions are determined for CWAs of interest. In this work, we determine the reaction rate for heterogeneous catalytic hydrolysis of eight commonly used G-agent simulants with zirconium-based MOFs. Of the simulants tested, only dimethyl chlorophosphate (DMCP), diisopropylfluorophosphate (DFP), and dimethyl p-nitrophenylphosphate (DMNP) exhibit the ability to be catalytically hydrolyzed in a manner similar to the G-agents by the MOFs studied. Two different base-catalyzed reaction mechanisms are proposed for the hydrolysis reaction on the different MOF secondary building units, and the effect of pH and buffer properties is determined using an N-ethylmorpholine (NEM) buffer at pH 8–10 and a 3-(cyclohexylamino)-1-propanesulofinic acid (CAPS) buffer at pH 10–11." @default.
• W2941001873 created "2019-05-03" @default.
• W2941001873 creator A5037007120 @default.
• W2941001873 creator A5080511577 @default.
• W2941001873 date "2019-08-01" @default.
• W2941001873 modified "2023-10-16" @default.
• W2941001873 title "Insight into organophosphate chemical warfare agent simulant hydrolysis in metal-organic frameworks" @default.
• W2941001873 cites W1946178027 @default.
• W2941001873 cites W1986238480 @default.
• W2941001873 cites W1998430268 @default.
• W2941001873 cites W2001922483 @default.
• W2941001873 cites W2002799357 @default.
• W2941001873 cites W2022085591 @default.
• W2941001873 cites W2022582494 @default.
• W2941001873 cites W2025831662 @default.
• W2941001873 cites W2029669944 @default.
• W2941001873 cites W2042397184 @default.
• W2941001873 cites W2043309554 @default.
• W2941001873 cites W2050343674 @default.
• W2941001873 cites W2050955268 @default.
• W2941001873 cites W2054006366 @default.
• W2941001873 cites W2054774531 @default.
• W2941001873 cites W2066991705 @default.
• W2941001873 cites W2069771769 @default.
• W2941001873 cites W2083026102 @default.
• W2941001873 cites W2085274123 @default.
• W2941001873 cites W2088559743 @default.
• W2941001873 cites W2091161882 @default.
• W2941001873 cites W2091664809 @default.
• W2941001873 cites W2094145140 @default.
• W2941001873 cites W2104739102 @default.
• W2941001873 cites W2104798614 @default.
• W2941001873 cites W2138133206 @default.
• W2941001873 cites W2144790873 @default.
• W2941001873 cites W2155579681 @default.
• W2941001873 cites W2171661037 @default.
• W2941001873 cites W2177858203 @default.
• W2941001873 cites W2233111524 @default.
• W2941001873 cites W2283564633 @default.
• W2941001873 cites W2322571666 @default.
• W2941001873 cites W2325339829 @default.
• W2941001873 cites W2335314823 @default.
• W2941001873 cites W2408778720 @default.
• W2941001873 cites W2466291603 @default.
• W2941001873 cites W2509134954 @default.
• W2941001873 cites W2517373925 @default.
• W2941001873 cites W2538094194 @default.
• W2941001873 cites W2591737146 @default.
• W2941001873 cites W2599379284 @default.
• W2941001873 cites W2605849292 @default.
• W2941001873 cites W2732367686 @default.
• W2941001873 cites W2784697201 @default.
• W2941001873 cites W2802924051 @default.
• W2941001873 cites W2899206852 @default.
• W2941001873 cites W3143879557 @default.
• W2941001873 cites W4254130853 @default.
• W2941001873 doi "https://doi.org/10.1016/j.jhazmat.2019.04.044" @default.
• W2941001873 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31059988" @default.
• W2941001873 hasPublicationYear "2019" @default.
• W2941001873 type Work @default.
• W2941001873 sameAs 2941001873 @default.
• W2941001873 citedByCount "46" @default.
• W2941001873 countsByYear W29410018732019 @default.
• W2941001873 countsByYear W29410018732020 @default.
• W2941001873 countsByYear W29410018732021 @default.
• W2941001873 countsByYear W29410018732022 @default.
• W2941001873 countsByYear W29410018732023 @default.
• W2941001873 crossrefType "journal-article" @default.
• W2941001873 hasAuthorship W2941001873A5037007120 @default.
• W2941001873 hasAuthorship W2941001873A5080511577 @default.
• W2941001873 hasBestOaLocation W29410018731 @default.
• W2941001873 hasConcept C101216236 @default.
• W2941001873 hasConcept C127413603 @default.
• W2941001873 hasConcept C150394285 @default.
• W2941001873 hasConcept C161176658 @default.
• W2941001873 hasConcept C161790260 @default.
• W2941001873 hasConcept C17744445 @default.
• W2941001873 hasConcept C178790620 @default.
• W2941001873 hasConcept C179104552 @default.
• W2941001873 hasConcept C179366358 @default.
• W2941001873 hasConcept C183696295 @default.
• W2941001873 hasConcept C185592680 @default.
• W2941001873 hasConcept C199539241 @default.
• W2941001873 hasConcept C2776588719 @default.
• W2941001873 hasConcept C2910751650 @default.
• W2941001873 hasConcept C42360764 @default.
• W2941001873 hasConcept C6557445 @default.
• W2941001873 hasConcept C86803240 @default.
• W2941001873 hasConcept C94412978 @default.
• W2941001873 hasConceptScore W2941001873C101216236 @default.
• W2941001873 hasConceptScore W2941001873C127413603 @default.
• W2941001873 hasConceptScore W2941001873C150394285 @default.
• W2941001873 hasConceptScore W2941001873C161176658 @default.
• W2941001873 hasConceptScore W2941001873C161790260 @default.
• W2941001873 hasConceptScore W2941001873C17744445 @default.
• W2941001873 hasConceptScore W2941001873C178790620 @default.
• W2941001873 hasConceptScore W2941001873C179104552 @default.
• W2941001873 hasConceptScore W2941001873C179366358 @default.

• next