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- W2941032378 abstract "Phase behavior of new aqueous two-phase systems (ATPSs) composed by 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) + copper sulfate (CuSO4) + water systems were determined experimentally at T = (283.15, 298.15, and 313.15) K. The phase diagrams obtained at the different study temperatures describe the liquid–liquid equilibrium (LLE) and, in some cases, the liquid–liquid–solid equilibrium for different mixture compositions. The effects of the temperature, composition, and ion exchange in the formation of this ATPS were available. The temperature had a remarkable effect on the position of phase diagrams. The decrease in temperature promoted phase separation indicating the exothermic character of formation of these ATPSs, and further, at temperatures of 283.15 and 298.15 K it was observed that there was phase inversion for some mixture compositions that occurred. The extent of the ionic exchange of the original ionic pairs between the phases in equilibrium was evaluated considering the electroneut..." @default.
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- W2941032378 date "2019-04-25" @default.
- W2941032378 modified "2023-09-24" @default.
- W2941032378 title "Phase Behavior in Aqueous Two-Phase Systems Based-Ionic Liquid Composed of 1-Butyl-3-methylimidazolium Tetrafluoroborate and Copper Sulfate in Different Temperatures" @default.
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- W2941032378 doi "https://doi.org/10.1021/acs.jced.8b01076" @default.
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