Matches in SemOpenAlex for { <https://semopenalex.org/work/W2941597668> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2941597668 endingPage "5740" @default.
- W2941597668 startingPage "5733" @default.
- W2941597668 abstract "Imazamox is a chiral herbicide that, in laboratory experiments in the dark, exhibits pronounced enantioselective biodegradation in certain soils. Imazamox also shows rapid photodegradation. However, which processes are predominant in the field is not clear. We conducted a set of soil incubation experiments under natural sunlight (and corresponding dark controls), using enantioselective LC–MS/MS analysis as a probe to distinguish biodegradation and photodegradation. Under dark conditions, imazamox was degraded enantioselectively. In contrast, degradation was nonenantioselective and 2× faster when the soil was exposed to sunlight, suggesting that biodegradation (in the dark) and photodegradation (under sunlight) were the predominant degradation processes. We also investigated the effectiveness of strategies that were proposed to exclude photodegradation in field studies, covering of soil with sand or irrigation after herbicide application. The sand cover did not prevent photodegradation. On the contrary, degradation was 10× faster than in the dark and nonenantioselective. Computer simulations supported the explanation that imazamox was transported upward by capillary flow due to evaporation onto the sand surface, where it was rapidly photodegraded. Irrigation postponed but not completely prevented photodegradation. For mobile substances susceptible to photodegradation, upward transport to the soil surface thus needs to be considered when deriving rates for biodegradation from field studies." @default.
- W2941597668 created "2019-05-03" @default.
- W2941597668 creator A5004434435 @default.
- W2941597668 creator A5031191525 @default.
- W2941597668 creator A5061719013 @default.
- W2941597668 creator A5081729079 @default.
- W2941597668 date "2019-04-24" @default.
- W2941597668 modified "2023-10-18" @default.
- W2941597668 title "Behavior of the Chiral Herbicide Imazamox in Soils: Enantiomer Composition Differentiates between Biodegradation and Photodegradation" @default.
- W2941597668 cites W1492486543 @default.
- W2941597668 cites W1969245681 @default.
- W2941597668 cites W1970779681 @default.
- W2941597668 cites W2009628198 @default.
- W2941597668 cites W2029552288 @default.
- W2941597668 cites W2029566337 @default.
- W2941597668 cites W2031355589 @default.
- W2941597668 cites W2063146634 @default.
- W2941597668 cites W2162604832 @default.
- W2941597668 cites W2166090013 @default.
- W2941597668 cites W2256916903 @default.
- W2941597668 cites W2323282490 @default.
- W2941597668 cites W2534867408 @default.
- W2941597668 cites W2940979418 @default.
- W2941597668 cites W4241314247 @default.
- W2941597668 doi "https://doi.org/10.1021/acs.est.8b07210" @default.
- W2941597668 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31017768" @default.
- W2941597668 hasPublicationYear "2019" @default.
- W2941597668 type Work @default.
- W2941597668 sameAs 2941597668 @default.
- W2941597668 citedByCount "9" @default.
- W2941597668 countsByYear W29415976682019 @default.
- W2941597668 countsByYear W29415976682020 @default.
- W2941597668 countsByYear W29415976682021 @default.
- W2941597668 countsByYear W29415976682022 @default.
- W2941597668 crossrefType "journal-article" @default.
- W2941597668 hasAuthorship W2941597668A5004434435 @default.
- W2941597668 hasAuthorship W2941597668A5031191525 @default.
- W2941597668 hasAuthorship W2941597668A5061719013 @default.
- W2941597668 hasAuthorship W2941597668A5081729079 @default.
- W2941597668 hasConcept C107872376 @default.
- W2941597668 hasConcept C157021035 @default.
- W2941597668 hasConcept C159390177 @default.
- W2941597668 hasConcept C159750122 @default.
- W2941597668 hasConcept C161790260 @default.
- W2941597668 hasConcept C162847780 @default.
- W2941597668 hasConcept C178790620 @default.
- W2941597668 hasConcept C185592680 @default.
- W2941597668 hasConcept C2779679103 @default.
- W2941597668 hasConcept C39432304 @default.
- W2941597668 hasConcept C41008148 @default.
- W2941597668 hasConcept C65165184 @default.
- W2941597668 hasConcept C76155785 @default.
- W2941597668 hasConceptScore W2941597668C107872376 @default.
- W2941597668 hasConceptScore W2941597668C157021035 @default.
- W2941597668 hasConceptScore W2941597668C159390177 @default.
- W2941597668 hasConceptScore W2941597668C159750122 @default.
- W2941597668 hasConceptScore W2941597668C161790260 @default.
- W2941597668 hasConceptScore W2941597668C162847780 @default.
- W2941597668 hasConceptScore W2941597668C178790620 @default.
- W2941597668 hasConceptScore W2941597668C185592680 @default.
- W2941597668 hasConceptScore W2941597668C2779679103 @default.
- W2941597668 hasConceptScore W2941597668C39432304 @default.
- W2941597668 hasConceptScore W2941597668C41008148 @default.
- W2941597668 hasConceptScore W2941597668C65165184 @default.
- W2941597668 hasConceptScore W2941597668C76155785 @default.
- W2941597668 hasIssue "10" @default.
- W2941597668 hasLocation W29415976681 @default.
- W2941597668 hasLocation W29415976682 @default.
- W2941597668 hasOpenAccess W2941597668 @default.
- W2941597668 hasPrimaryLocation W29415976681 @default.
- W2941597668 hasRelatedWork W2059012695 @default.
- W2941597668 hasRelatedWork W2070735392 @default.
- W2941597668 hasRelatedWork W2316083425 @default.
- W2941597668 hasRelatedWork W2361480099 @default.
- W2941597668 hasRelatedWork W2365004626 @default.
- W2941597668 hasRelatedWork W2374886535 @default.
- W2941597668 hasRelatedWork W2899084033 @default.
- W2941597668 hasRelatedWork W2941597668 @default.
- W2941597668 hasRelatedWork W3162471139 @default.
- W2941597668 hasRelatedWork W654972238 @default.
- W2941597668 hasVolume "53" @default.
- W2941597668 isParatext "false" @default.
- W2941597668 isRetracted "false" @default.
- W2941597668 magId "2941597668" @default.
- W2941597668 workType "article" @default.