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• W2942304411 endingPage "3416" @default.
• W2942304411 startingPage "3412" @default.
• W2942304411 abstract "The reactivity of boronate complexes which resemble donor–acceptor cyclopropanes is described. The enantioenriched cyclopropyl boronate complexes were shown to undergo concerted 1,2-metalate rearrangement/ring opening upon activation with a Lewis acid. This method provides atom-efficient access to optically active γ-carbonyl boronic esters in moderate to excellent yields with complete enantiospecificity. Furthermore, a three-component variant of the reaction was established through in situ alkylation, and the synthetic utility of the products as chiral building blocks was demonstrated." @default.
• W2942304411 created "2019-05-03" @default.
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• W2942304411 date "2019-04-24" @default.
• W2942304411 modified "2023-10-16" @default.
• W2942304411 title "Strain Release of Donor–Acceptor Cyclopropyl Boronate Complexes" @default.
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• W2942304411 doi "https://doi.org/10.1021/acs.orglett.9b01152" @default.
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