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- W2942525366 abstract "The mechanism of 1,2-aryl shifts in the Wittig rearrangement of α-metallated benzyl aryl ethers has been investigated by a detailed examination of the behavior of the following ethers: benzyl phenyl ether, benzyl para-tert-butyl- and meta-tert-butyl-phenyl ethers, benzyl 2-bromo-4-tert-butylphenyl ether and dibenzo[b,d] pyran. The failure to trap any aldehyde intermediate, the ease of rearrangement for the pyran, the lack of evidence for an aryne intermediate with the benzyl butyl ethers and other circumstantial evidence have led to the proposal of an intramolecular pathway in which radical pairs are generated and then collapse to the isomeric carbinolate." @default.
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- W2942525366 date "1974-02-01" @default.
- W2942525366 modified "2023-10-07" @default.
- W2942525366 title "Rearrangements of organometallic compounds" @default.
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- W2942525366 doi "https://doi.org/10.1016/s0022-328x(00)82263-9" @default.
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