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- W2942702372 abstract "Dinickel complexes promote stoichiometric Pauson–Khand reactions of enynes and CO (g). However, catalytic turnover is precluded by the strong binding of CO to the Ni2 active site. This article describes the use of M(CO)x reagents as stoichiometric CO precursors in Ni2-catalyzed carbonylation reactions. As part of these studies, well-defined heterotrinuclear Ni2Fe, Ni2Co, and Ni2Mn carbonyl clusters are synthesized using the [NDI]Ni2 platform as a template (NDI = naphthyridine–diimine)." @default.
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- W2942702372 date "2019-06-01" @default.
- W2942702372 modified "2023-10-17" @default.
- W2942702372 title "Dinickel catalyzed carbonylation reactions using metal carbonyl reagents as CO sources" @default.
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- W2942702372 doi "https://doi.org/10.1016/j.tet.2019.04.064" @default.
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