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- W2942719872 abstract "A series of new carbonyl dichromium complexes bearing aryl germanes as ligands were prepared using improved approaches. The thermal reaction of Cr(CO) 6 ( 1 ) with Me 3 GeGePh 3 ( 3 ) led to the formation of Me 3 GeGePh[(η 6 ‐C 6 H 5 )Cr(CO) 3 ] 2 ( 3a ). The lithiation of [(η 6 ‐C 6 H 6 )Cr(CO) 3 ] ( 2 ) with n BuLi followed by the addition of Me 2 GeCl 2 ( 4 ) or ClGeMe 2 GeMe 2 Cl ( 5 ) gave Me 2 Ge[(η 6 ‐C 6 H 5 )Cr(CO) 3 ] 2 ( 4a ) and [(OC) 3 Cr(η 6 ‐C 6 H 5 )]GeMe 2 GeMe 2 [(η 6 ‐C 6 H 5 )Cr(CO) 3 ] ( 5a ), respectively. The molecular structures of 3a and 4a , in their crystal forms, were studied by X‐ray diffraction analysis. The crystals of oligogermane 3a have shown to undergo a fully reversible phase transition at 160 K without any sign of decomposition. The complexes synthesized were also studied by multinuclear NMR, IR and UV/Vis spectroscopy, DFT calculations and electrochemistry. The presence of a Cr(CO) 3 group in a range of oligogermanes has shown to impact on the physical and chemical properties of the compounds." @default.
- W2942719872 created "2019-05-09" @default.
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- W2942719872 date "2019-05-21" @default.
- W2942719872 modified "2023-10-18" @default.
- W2942719872 title "Aryl Germanes as Ligands for Transition Polymetallic Complexes: Synthesis, Structure, and Properties" @default.
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- W2942719872 cites W1967352625 @default.
- W2942719872 cites W1971432803 @default.
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- W2942719872 cites W1976586746 @default.
- W2942719872 cites W1986952603 @default.
- W2942719872 cites W1988168939 @default.
- W2942719872 cites W1996544546 @default.
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- W2942719872 cites W2002305893 @default.
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- W2942719872 cites W2005224496 @default.
- W2942719872 cites W2005422230 @default.
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- W2942719872 doi "https://doi.org/10.1002/ejic.201900316" @default.
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