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• W2942765329 endingPage "159" @default.
• W2942765329 startingPage "152" @default.
• W2942765329 abstract "Abstract A new Zn(II)-based coordination complex, [Zn(L)2]·(CH3OH)0.5·(H2O)2 (1) (L = 3-chloro-6-(3-methyl-5-phenyl-1H-pyrazol-1-yl) picolinic acid) has been synthesized by solvothermal condition. The uncoordinated oxygen atoms in the compound can be used as active sites for post-synthetic modifications. Therefore, compound 1 can act as a precursor material for coating lanthanides. The Ln@1 (Tb@1 and Eu@1) materials showed characteristic emission properties of Ln3+ ions. These emissions are selectively quenched by nitroaromatic compounds in ethanol with good sensitivity. The result illustrated that the materials selectively detect of 2,4,6-trinitrophenol (TNP), 2,4-dinitroaniline (2,4-NA) with higher efficiency (Ksv>104 M−1) compared with other nitroaromatic compounds, including 2,4-dinitrotoluene (2,4-DNT), 2,6-dinitrotoluene (2,6-DNT), nitrobenzene (NB), 4-nitrophenol (4-NP), 4-nitrotoluene (4-NT). Furthermore, the fluorescent paper strips were prepared in order to make them as portable sensing agents. In addition, a probable sensing mechanism was also discussed in this paper." @default.
• W2942765329 created "2019-05-09" @default.
• W2942765329 creator A5002638175 @default.
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• W2942765329 creator A5081250822 @default.
• W2942765329 creator A5085083319 @default.
• W2942765329 date "2019-06-01" @default.
• W2942765329 modified "2023-09-27" @default.
• W2942765329 title "Ln-incorporated coordination complexes as fluorescence sensor for selective detection nitroaromatic compounds" @default.
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• W2942765329 doi "https://doi.org/10.1016/j.matchemphys.2019.04.068" @default.
• W2942765329 hasPublicationYear "2019" @default.
• W2942765329 type Work @default.
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