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- W2943083359 abstract "The PH and AsH acidities of primary and secondary phosphines and arsines have been determined by metal-hydrogen exchange between substituted alkali phosphides and arsides and hydrocarbons, alcohols and amines, respectively. Compared with CH, 0H and NH acids, there results, in general, the following sequence of acidities: NaNH2 reacts with aryl-substituted primary and secondary phosphines and arsines to form the corresponding sodium salts. M2ER and REH2 yield MEHR (E = P, As; M = Li, K) in a type of acid-base double decomposition. An hand des metall-wassertoft-austausches zwischen P(As)-substituierten alkaliphosphiden (-arsiden) und kohlenwassertoften, alkohclen sowie aminen wird die P-H- bzw. As-H-acidität primärer und sekundärer Phosphine bzw. Arsine ermittelt. Im Vergleich zu C-H-, O-H- und N-H-Säuren resultiert allgemein folgende aciditätsabstufung: NaNH2 reagiert mit arylsubstituierten primären und sekundären Phosphinen bzw. Arsinen zu den entsprechenden Natriumsalzen. M2ER und REH2 (E P, As; M = Li, K) liefern im Sinne einer Säure-Base-Komproportionierung MEHR." @default.
- W2943083359 created "2019-05-09" @default.
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- W2943083359 date "1965-01-01" @default.
- W2943083359 modified "2023-10-16" @default.
- W2943083359 title "Alkali-phosphorverbindungen und ihr reaktives verhalten" @default.
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- W2943083359 doi "https://doi.org/10.1016/s0022-328x(00)82739-4" @default.
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