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- W2943668178 abstract "Previous experimental results shows mixed Mannich base (C15H15NO) and Na2WO4 have demonstrated excellent corrosion prevention, and the best corrosion inhibition efficiency is 96.19% when the mixing ratio of the two components is 1:1. In order to clearly understand to inhibition mechanism, molecular dynamics were used to model the inhibition effects of C15H15NO or Na2WO4 molecule on the iron surface. The simulation results indicate there are synergistic effect between C15H15NO and Na2WO4. the synergistic effect has three main factors: for one, the synergistic effect is due to the WO42− (small) can fill in the voids of the C15H15NO (big), the mixed inhibitor film is denser than single inhibitor film; moreover, the WO42− forms H-bond group with H3O+, which makes corrosive particles harder to pass through adsorption film, simultaneously; In addition, the mixed inhibitor significantly reduces the free charges and ions on Fe surface, which makes metal structure is more stable." @default.
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- W2943668178 date "2019-04-30" @default.
- W2943668178 modified "2023-10-16" @default.
- W2943668178 title "Investigation on the synergy mechanism of mixed inhibitors – Mannich base and Na<sub>2</sub>WO<sub>4</sub> on Fe surface by molecules dynamic simulation" @default.
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- W2943668178 doi "https://doi.org/10.1080/08927022.2019.1610953" @default.
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