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- W2943758707 abstract "Abstract The selective hydrodefluorination of hexafluoropropene to HFO‐1234ze and HFO‐1234yf can be achieved by reaction with simple group 13 hydrides of the form EH 3 ⋅ L (E=B, Al; L=SMe 2 , NMe 3 ). The chemoselectivity varies depending on the nature of the group 13 element. A combination of experiments and DFT calculations show that competitive nucleophilic vinylic substitution and addition‐elimination mechanisms involving hydroborated intermediates lead to complementary selectivities. magnified image" @default.
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- W2943758707 date "2019-05-23" @default.
- W2943758707 modified "2023-10-12" @default.
- W2943758707 title "Selective Hydrodefluorination of Hexafluoropropene to Industrially Relevant Hydrofluoroolefins" @default.
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- W2943758707 doi "https://doi.org/10.1002/adsc.201900234" @default.
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