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• W2943787400 abstract "Here, we present a robust synthetic route to a 2′-amino-2′-deoxyadenosine phosphoramidite building block for automated RNA solid-phase synthesis. The thus accessible 2′-amino-modified RNA finds applications in the evaluation of hydrogen-bond networks in folded RNA, such as riboswitches or ribozymes. In this context, we previously implemented the here described 2′-amino-2′-deoxyadenosine building block in a comparative study on self-cleaving pistol ribozymes to shed light on structural versus catalytic roles of active-site 2′-OH groups in the reaction mechanism." @default.
• W2943787400 created "2019-05-09" @default.
• W2943787400 creator A5036442340 @default.
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• W2943787400 date "2019-04-29" @default.
• W2943787400 modified "2023-10-16" @default.
• W2943787400 title "Efficient access to N-trifluoroacetylated 2′-amino-2′-deoxyadenosine phosphoramidite for RNA solid-phase synthesis" @default.
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• W2943787400 doi "https://doi.org/10.1007/s00706-019-02390-x" @default.
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