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• W2943900548 abstract "Abstract An assembly strategy for metal nanoclusters using electrostatic interactions with weak interactions, such as C−H⋅⋅⋅π and π⋅⋅⋅π interactions in which cationic [Ag 26 Au(2‐EBT) 18 (PPh 3 ) 6 ] + and anionic [Ag 24 Au(2‐EBT) 18 ] − nanoclusters gather and assemble in an unusual alternating array stacking structure is presented. [Ag 26 Au(2‐EBT) 18 (PPh 3 ) 6 ] + [Ag 24 Au(2‐EBT) 18 ] − is a new compound type, a double nanocluster ion compound (DNIC). A single nanocluster ion compound (SNIC) [PPh 4 ] + [Ag 24 Au(2‐EBT) 18 ] − was also synthesized, having a k‐vector‐differential crystallographic arrangement. [PPh 4 ] + [Ag 24 Au(2,4‐DMBT) 18 ] − adopts a different assembly mode from both [Ag 26 Au(2‐EBT) 18 (PPh 3 ) 6 ] + [Ag 24 Au(2‐EBT) 18 ] − and [PPh 4 ] + [Ag 24 Au(2‐EBT) 18 ] − . Thus, the striking packing differences of [Ag 26 Au(2‐EBT) 18 (PPh 3 ) 6 ] + [Ag 24 Au(2‐EBT) 18 ] − , [PPh 4 ] + [Ag 24 Au(2‐EBT) 18 ] − and the existing [PPh 4 ] + [Ag 24 Au(2,4‐DMBT) 18 ] − from each other indicate the notable influence of ligands and counterions on the self‐assembly of nanoclusters." @default.
• W2943900548 created "2019-05-16" @default.
• W2943900548 creator A5010168002 @default.
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• W2943900548 creator A5058683121 @default.
• W2943900548 creator A5066833385 @default.
• W2943900548 creator A5071069893 @default.
• W2943900548 date "2019-06-21" @default.
• W2943900548 modified "2023-10-18" @default.
• W2943900548 title "Alternating Array Stacking of Ag₂₆Au and Ag₂₄Au Nanoclusters" @default.
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• W2943900548 doi "https://doi.org/10.1002/ange.201900831" @default.
• W2943900548 hasPublicationYear "2019" @default.
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