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- W2943936036 endingPage "110890" @default.
- W2943936036 startingPage "110890" @default.
- W2943936036 abstract "Lagerstroemia speciosa leaf extract (LSLE) was examined as corrosion mitigating agent against mild steel in 1 M HCl. The extract was characterized by GC–MS and FTIR. Weight loss (WL), potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), SEM- EDX, AFM, UV–Vis spectroscopy and DFT studies were performed to examine corrosion mitigation performance of LSLE. As revealed by WL the extract was above 94% efficient at the concentration of 500 ppm and 333 K. Adsorption of LSLE on mild steel surface is spontaneous and follows Langmuir isotherm model. Mixed type inhibition with anodic predominance was revealed by PDP results. EIS data revealed the formation of inhibitive film on metal surface by the active groups of the extract. SEM and AFM show a better morphological image and reduced surface roughness in the presence of LSLE. UV–Vis results indicate Fe-LSLE complex formation during corrosion reaction. DFT has been conducted to correlate the inhibition efficiency with the molecular structure of active species present in the extract. Quantum parameters and Molecular dynamic simulation helps in correlating the molecular structure and adsorption strength with inhibition efficiency. ANOVA statistical test was conducted to compare the inhibition efficiencies obtained by using different techniques and the data reveals that they are significantly not different." @default.
- W2943936036 created "2019-05-16" @default.
- W2943936036 creator A5001755495 @default.
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- W2943936036 date "2019-07-01" @default.
- W2943936036 modified "2023-10-14" @default.
- W2943936036 title "Corrosion mitigation of mild steel in acidic medium using Lagerstroemia speciosa leaf extract: A combined experimental and theoretical approach" @default.
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- W2943936036 doi "https://doi.org/10.1016/j.molliq.2019.110890" @default.
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