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- W2943955490 abstract "Abstract A sequence of a Baeyer–Villiger oxidation and a Lewis acid‐promoted reduction of the resulting formate with Et 3 SiH enabled the metal‐free formal decarbonylation of tertiary and secondary aliphatic aldehydes. The new methodology mimics the biosynthetic decarbonylation pathway through oxidative C−C bond cleavage rather than the C(O)−H bond activation known from conventional Tsuji–Wilkinson‐type reactions. The substrate scope is complementary to existing transition‐metal‐catalyzed protocols." @default.
- W2943955490 created "2019-05-16" @default.
- W2943955490 creator A5002792140 @default.
- W2943955490 creator A5034305035 @default.
- W2943955490 date "2019-05-24" @default.
- W2943955490 modified "2023-10-12" @default.
- W2943955490 title "Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature" @default.
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- W2943955490 doi "https://doi.org/10.1002/chem.201902082" @default.
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