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• W2944335959 abstract "We reported herein the temperature-dependent dielectric properties of K0.8M0.4Ti1.6O4 (M = Ni, Zn) lepidocrocite titanate ceramics at the frequency f of 103, 104 and 105 Hz. This titanate is an example of layered alkali titanium oxides possessing two-dimensional (2D) sheets of edge-shared TiO6 octahedra, in contrast to other widely studied materials with mostly corner-shared TiO6 motifs. The giant dielectric constants ε′ ∼104 and the dielectric losses tan δ ∼ 0.5–2 were obtained upon heating from RT to 250 °C. These values in our water-free ceramics are comparable to those previously reported in lepidocrocite titanate and related structures containing up to 15%wt water. The results were explained considering (i) Maxwell-Wagner polarization of interlayer species, and (ii) the possible formation of internal barrier layer capacitors (IBLCs) via the oxidized surfaces." @default.
• W2944335959 created "2019-05-16" @default.
• W2944335959 creator A5059643543 @default.
• W2944335959 creator A5069882075 @default.
• W2944335959 date "2019-01-02" @default.
• W2944335959 modified "2023-10-15" @default.
• W2944335959 title "Giant dielectric constants in K_0.8M_0.4Ti_1.6O₄ (M = Ni, Zn) lepidocrocite-type layered titanate ceramics" @default.
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• W2944335959 doi "https://doi.org/10.1080/10584587.2019.1570024" @default.
• W2944335959 hasPublicationYear "2019" @default.
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