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- W2944437032 abstract "Abstract A simple, inexpensive and stereoselective synthesis of novel functionalized cyclohexanone derivatives via the reaction of acetoacetamide with aromatic aldehydes in ethanol at room temperature is described. Additionally, the presence of substituents such as NO 2 and Cl in the ortho -position of the aldehyde aromatic ring resulted in the formation of novel piperidines. The use of Lewis acids such as iron(III) chloride and bismuth(III) nitrate as catalysts led to autocondensation of acetoacetamide and the formation of 2,4-dimethyl-6-oxo-1,6-dihydropyridine-3-carboxamide." @default.
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- W2944437032 date "2019-06-01" @default.
- W2944437032 modified "2023-10-18" @default.
- W2944437032 title "Stereoselective synthesis of novel functionalized cyclohexanone derivatives via the condensation of aromatic aldehydes with acetoacetamide and the influence of the ortho-effect and autocondensation" @default.
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- W2944437032 doi "https://doi.org/10.1016/j.tetlet.2019.05.023" @default.
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