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- W2944625709 abstract "Treatment of MOF-5 with NbCl4(THF)2 in acetonitrile leads to incorporation of Nb(iv) centers in a fashion that diverges from the established cation metathesis reactivity of this iconic material. A combination of X-ray absorption spectroscopy analysis and reactivity studies altogether supported by density functional theory computational studies document an unprecedented binding mode for the Zn4O(O2C-)6 secondary building units (SBUs), which in Nb(iv)-MOF-5 function as κ2-chelating ligands for NbCl4 moieties, with no exchange of Zn2+ observed. This unusual reactivity expands the portfolio of post-synthetic modification techniques available for MOFs, exemplified here by MOF-5, and underscores the diverse coordination environments offered by this and potentially other MOFs towards heterometal species." @default.
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- W2944625709 date "2019-01-01" @default.
- W2944625709 modified "2023-10-16" @default.
- W2944625709 title "<i>Quo vadis niobium</i>? Divergent coordination behavior of early-transition metals towards MOF-5" @default.
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- W2944625709 doi "https://doi.org/10.1039/c9sc01553a" @default.
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