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- W2944653705 abstract "A series of cyano-bridged homotrinuclear Re(I) complexes with the general formula of {[Re]′[Re][Re]′}+ {[Re]′ = −[ReI(CO)2(LL)(X)]; [Re] = −[(NC)ReI(CO)2(phen)(CN)]–; LL = diimine, diphosphine, or two carbonyl ligands; X = triphenylphosphine or carbonyl ligand} and the corresponding mononuclear complex analogues were synthesized. The structures of most of the trinuclear Re(I) complexes have been determined by X-ray crystallography. The relative orientations of peripheral to central Re(I) units in these structures vary considerably. The photophysical properties of these trinuclear Re(I) complexes have been examined. Except for the trinuclear Re(I) complex with Br2phen ligand, all the other triads display orange to red photoluminescence derived from the 3MLCT [dπ(Re) → π*(phen)] origin of the central Re(I) unit, suggestive of efficient energy transfer between the peripheral chromophores and the central unit. In addition to the efficient energy transfer processes between the Re(I) chromophores in these trinuclear complexes, the ability of the [NC–Re–CN] bridging ligands for electronic coupling between the rhenium metal centers is evidenced by ca. 0.2–0.3 V separation of the two rhenium metal-based oxidation potentials of the chemically equivalent peripheral units." @default.
- W2944653705 created "2019-05-16" @default.
- W2944653705 creator A5000845869 @default.
- W2944653705 creator A5014813334 @default.
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- W2944653705 creator A5052887839 @default.
- W2944653705 creator A5067492712 @default.
- W2944653705 creator A5070948725 @default.
- W2944653705 creator A5088594718 @default.
- W2944653705 date "2019-05-07" @default.
- W2944653705 modified "2023-10-03" @default.
- W2944653705 title "Electronic Communication in Luminescent Dicyanorhenate-Bridged Homotrinuclear Rhenium(I) Complexes" @default.
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- W2944653705 doi "https://doi.org/10.1021/acs.inorgchem.9b00072" @default.
- W2944653705 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31063368" @default.
- W2944653705 hasPublicationYear "2019" @default.
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