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• W2944844724 endingPage "3627" @default.
• W2944844724 startingPage "3617" @default.
• W2944844724 abstract "An efficient protocol for C–H condensation of hypervalent iodine compounds toward arenes in fluoroalcohols has been applied to the recyclable preparation of mesityl iodonium(III) salts. The electrophilicities of [hydroxy(tosyloxy)iodo]mesitylene (MesI(OH)OTs) and iodomesitylene diacetate (MesI(OAc)2) are suitably enhanced in 2,2,2-trifluoroethanol. A series of nucleophilic aromatic compounds react smoothly with MesI(OH)OTs and MesI(OAc)2 or in situ hypervalent iodine(III) species, generated from iodomesitylene, to provide the target mesityl iodonium(III) salts in good yields at room temperature with broad functional group tolerance. This C–H condensation strategy merits high para-regioselectivities during the diaryliodonium(III) salt formation, but the major limitation in the case of low-reactive aromatic substrates is byproduct formation resulting from the self-condensation of the nucleophilic mesitylene ring in MesI(OH)OTs and MesI(OAc)2." @default.
• W2944844724 created "2019-05-29" @default.
• W2944844724 creator A5015841809 @default.
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• W2944844724 creator A5079108301 @default.
• W2944844724 creator A5084911046 @default.
• W2944844724 creator A5088230913 @default.
• W2944844724 date "2019-06-01" @default.
• W2944844724 modified "2023-10-14" @default.
• W2944844724 title "Recyclable synthesis of mesityl iodonium(III) salts" @default.
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