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- W2944848835 abstract "Abstract A novel 3D cationic metal–organic framework, {[AgTPB]∙SbF6}n (namely 1), based on AgI and 1,2,4,5-tetra(4-pyridyl) benzene (TPB) was successfully generated under the diffusion synthesis method. The as-synthesized crystal has been investigated and characterized by physicochemical and spectroscopic methods in detail, including single crystal X-ray diffraction, powder X-ray diffraction, UV–Vis spectra, gas/liquid sorption, as well as thermogravimetric analysis. The counter anion SbF6− coming from AgSbF6 exists in the pores of MOF 1. The activated 1 can selectively adsorb CO2 over CH4, and H2O over C2H5OH. Furthermore, it also can be used as a rapid anion exchange MOF for Cr2O72− in water system at room temperature." @default.
- W2944848835 created "2019-05-29" @default.
- W2944848835 creator A5011751747 @default.
- W2944848835 creator A5044248804 @default.
- W2944848835 date "2019-10-01" @default.
- W2944848835 modified "2023-10-16" @default.
- W2944848835 title "A novel 3D AgI cationic metal–organic framework based on 1,2,4,5-tetra(4-pyridyl) benzene with selective adsorption of CO2 over CH4, H2O over C2H5OH, and trapping Cr2O72–" @default.
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- W2944848835 doi "https://doi.org/10.1016/j.molstruc.2019.05.070" @default.
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