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- W2944987320 abstract "We have successfully synthesized sulfonated core-corona polymer microsphere 3 by the surface-initiated ATRP (SI-ATRP) of achiral vinyl monomer and phenylsulfonated styrene with monodispersed polymer microsphere having benzyl chloride moiety 1 prepared via precipitation polymerization as a macroinitiator, followed by the treatment of NaOH. N-(9-Anthracenemethyl)-cinchonidinium chloride 4 was successfully immobilized onto the side chain of corona of 3 by the ion exchange reaction to afford core-corona polymer microsphere-supported chiral cinchonidinium salt 5. These chiral catalysts were used as polymeric chiral organocatalysts in the asymmetric alkylation reactionof a glycine derivative. We found that the size of core, nature and length of corona, grafting density, as well as the degree of crosslinking significantly affected on the catalytic reactivity. Amoung them, 5d20hC20 showed good reactivity and excellent enantioselectivity (up to <99%), higher than those corresponding molecular catalyst 4, microshere catalyst M-Cat, as well as linear polymeric catalyst St0Cat100. 5d20hC20 could be reused several times without loss of the enantioselectivity." @default.
- W2944987320 created "2019-05-29" @default.
- W2944987320 creator A5002305257 @default.
- W2944987320 creator A5019111766 @default.
- W2944987320 creator A5073376153 @default.
- W2944987320 creator A5074244941 @default.
- W2944987320 date "2019-08-01" @default.
- W2944987320 modified "2023-10-13" @default.
- W2944987320 title "Synthesis of core-corona polymer microsphere-supported cinchonidinium salt and its application to asymmetric synthesis" @default.
- W2944987320 cites W1966863664 @default.
- W2944987320 cites W1975994522 @default.
- W2944987320 cites W1976875348 @default.
- W2944987320 cites W1977909942 @default.
- W2944987320 cites W1978788662 @default.
- W2944987320 cites W1978872559 @default.
- W2944987320 cites W1979975654 @default.
- W2944987320 cites W1981781450 @default.
- W2944987320 cites W1986584347 @default.
- W2944987320 cites W1990371948 @default.
- W2944987320 cites W1994436014 @default.
- W2944987320 cites W1995538376 @default.
- W2944987320 cites W1997930025 @default.
- W2944987320 cites W1999129552 @default.
- W2944987320 cites W2001047058 @default.
- W2944987320 cites W2001280311 @default.
- W2944987320 cites W2001530486 @default.
- W2944987320 cites W2001707540 @default.
- W2944987320 cites W2003038796 @default.
- W2944987320 cites W2003297400 @default.
- W2944987320 cites W2003494448 @default.
- W2944987320 cites W2004720579 @default.
- W2944987320 cites W2006611155 @default.
- W2944987320 cites W2012001290 @default.
- W2944987320 cites W2013175186 @default.
- W2944987320 cites W2024201207 @default.
- W2944987320 cites W2026281585 @default.
- W2944987320 cites W2029630821 @default.
- W2944987320 cites W2034591628 @default.
- W2944987320 cites W2035291783 @default.
- W2944987320 cites W2037600345 @default.
- W2944987320 cites W2039085236 @default.
- W2944987320 cites W2040062577 @default.
- W2944987320 cites W2040223160 @default.
- W2944987320 cites W2043387494 @default.
- W2944987320 cites W2044915216 @default.
- W2944987320 cites W2047805110 @default.
- W2944987320 cites W2048704981 @default.
- W2944987320 cites W2049005582 @default.
- W2944987320 cites W2049221123 @default.
- W2944987320 cites W2050620648 @default.
- W2944987320 cites W2052169364 @default.
- W2944987320 cites W2055393399 @default.
- W2944987320 cites W2056809829 @default.
- W2944987320 cites W2059542297 @default.
- W2944987320 cites W2061682717 @default.
- W2944987320 cites W2062373564 @default.
- W2944987320 cites W2063283966 @default.
- W2944987320 cites W2071276269 @default.
- W2944987320 cites W2074866595 @default.
- W2944987320 cites W2079374957 @default.
- W2944987320 cites W2079777505 @default.
- W2944987320 cites W2088538011 @default.
- W2944987320 cites W2089023732 @default.
- W2944987320 cites W2095359487 @default.
- W2944987320 cites W2106563217 @default.
- W2944987320 cites W2119961090 @default.
- W2944987320 cites W2126947909 @default.
- W2944987320 cites W2128968199 @default.
- W2944987320 cites W2129370270 @default.
- W2944987320 cites W2134467667 @default.
- W2944987320 cites W2140512856 @default.
- W2944987320 cites W2143298975 @default.
- W2944987320 cites W2144122182 @default.
- W2944987320 cites W2146699334 @default.
- W2944987320 cites W2146854707 @default.
- W2944987320 cites W2156396225 @default.
- W2944987320 cites W2158814184 @default.
- W2944987320 cites W2159273177 @default.
- W2944987320 cites W2164212281 @default.
- W2944987320 cites W2169173700 @default.
- W2944987320 cites W2170672511 @default.
- W2944987320 cites W2316529693 @default.
- W2944987320 cites W2321723093 @default.
- W2944987320 cites W2590754983 @default.
- W2944987320 cites W2807963173 @default.
- W2944987320 cites W2949757154 @default.
- W2944987320 cites W2949897983 @default.
- W2944987320 cites W2950236765 @default.
- W2944987320 cites W2950266152 @default.
- W2944987320 cites W2951031486 @default.
- W2944987320 cites W2952917484 @default.
- W2944987320 cites W4231020173 @default.
- W2944987320 doi "https://doi.org/10.1016/j.mcat.2019.110392" @default.
- W2944987320 hasPublicationYear "2019" @default.
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