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- W2945047984 abstract "The origin of variations in 186Os/188Os ratios amongst mantle-derived basaltic and komatiitic lavas remains controversial, with opposing models arguing for deep core-mantle versus shallow mantle sources. Crustal contamination has generally not been favored due to the low Os contents of such sources, meaning that variations in 186Os/188Os would require involvement of extremely high proportions of crustal material. Here we re-examine crustal contamination as an effective means for generating significant 186Os/188Os variations in Earth materials. Using chromitites and peridotites from the Stillwater, Muskox and Rum layered intrusions, we show that radiogenic 186Os/188Os ratios are correlated with 187Os/188Os ratios and can only be explained by shallow-level mixing processes and crustal contamination. The samples have δ186Os ([{(186Os/188Ossample[t]/186Os/188OsPM(t)) − 1} × 1000], where the modern primitive mantle [PM] 186Os/188Os is 0.1198388) values ranging between 0.04 to 0.15 for the ∼2.7 Ga Stillwater Igneous Complex, −0.05 to 0.17 for the ∼1.27 Ga Muskox Intrusion, and 0.02 to 0.13 for the ∼0.06 Ga Rum Layered Suite. The highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, Re) contents of the chromitites and peridotites can be modeled through high sulfide-melt partitioning (typically >8000) and emphasize the role of S-saturation and HSE scavenging. Considering the high sulfide-melt partitioning and accounting for high silicate melt to sulfide melt ratios (R-factors), it is possible to explain the variations in 186Os–187Os in layered intrusions using calculated Os isotope crustal evolution growth models. These calculations indicate that <4% of ancient high Pt/Os crustal contributions can explain the composition of the chromitites and peridotites that were examined. Our observations are consistent with published models for chromitite genesis that invoke either crustal melt-primitive melt mixing, or cumulate assimilation. A crustal origin for radiogenic 186Os is a possible cause for 186Os/188Os ratio variations observed in some komatiites. It is more difficult to explain radiogenic 186Os/188Os measured in Hawaiian lavas by crustal contamination processes. Instead, ancient high Pt/Os oceanic crust, shallow mantle sources such as metasomatic sulfide, or metal-rich large low-shear wave velocity provinces at the core-mantle boundary, all remain valid explanations." @default.
- W2945047984 created "2019-05-29" @default.
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- W2945047984 date "2019-08-01" @default.
- W2945047984 modified "2023-10-14" @default.
- W2945047984 title "Ancient high Pt/Os crustal contaminants can explain radiogenic 186Os in some intraplate magmas" @default.
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- W2945047984 doi "https://doi.org/10.1016/j.epsl.2019.04.039" @default.
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