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- W2945123857 abstract "Polarized-light optical, atomic-force, electron scanning microscopies and X-ray techniques were applied to reveal and analyze a highly anisotropic crystal aggregation into Janus-face spherulites in poly(butylene succinate) (PBSu) induced by crystallization in presence of molten poly(ethylene oxide) (PEO) at Tc = 70 °C. The dual-face (i.e., Janus-face) PBSu spherulites are distinguished with various fractions of two different lamellar assemblies filling the spherulites’ two portions. The Janus-face PBSu crystals (straight dendritic and circularly ring-banded lamellae) become significant only when the PEO content is kept at 20–30 wt% in the blended PBSu/PEO mixtures at Tc = 70 °C, with no top-cover confinement. That is, existence of Janus-faced spherulite is highly kinetics-selective for favorable nucleation to highly anisotropic growth into co-existence of two faces. Mechanisms of unique nucleation and interior lamellae assembly into the peculiar Janus-face PBSu spherulites are analyzed and discussed." @default.
- W2945123857 created "2019-05-29" @default.
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- W2945123857 date "2019-08-01" @default.
- W2945123857 modified "2023-10-17" @default.
- W2945123857 title "Surface-relief and interior lamellar assembly in Janus-face spherulites of Poly(butylene succinate) crystallized with Poly(ethylene oxide)" @default.
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- W2945123857 doi "https://doi.org/10.1016/j.polymer.2019.05.048" @default.
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