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- W2945135579 abstract "Ten novel C21 pregnane glycosides, extensumside C-L (1-10), were isolated as highly sweet-tasting substances from the edible pericarps of Myriopteron extensum (Wight) K. Schum by sensory-guided fractionation and purification. Their structures were determined through 1D and 2D NMR, such as HSQC, HMBC, 1H-1H COSY, HSQC-TOCSY, and ROESY, as well as other spectroscopic analysis combined with chemical evidence. These compounds shared the same aglycone, 3β,16α-dihydroxy-pregn-5-en-20-one, and contained the deoxysugar chain and the glucose chain which were linked to C-3 and C-16 of the aglycone, respectively. The sweetness potency was evaluated by a human sensory panel test and preliminary structure-taste relationship was discussed. The sweetness intensities of these compounds are between 50 and 400 times greater than that of sucrose. Furthermore, quantitation analyses of compounds 1, 3, 4, and 6 in different parts of M. extensum indicated that the concentrations of these sweet components in the pericarps are obviously higher than those in stems and roots." @default.
- W2945135579 created "2019-05-29" @default.
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- W2945135579 date "2016-12-01" @default.
- W2945135579 modified "2023-09-26" @default.
- W2945135579 title "New Sweet-Tasting C21-Pregnane Glycosides from Pericarps of <i>Myriopteron extensum</i>" @default.
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- W2945135579 doi "https://doi.org/10.1021/acs.jafc.6b04121" @default.
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