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- W2945140809 abstract "Supramolecular assembly of well-defined discrete architectures has been of great interest due to the tunable properties of these structures in functional materials and bio-mimicking. While metal-coordination-driven assembly has been extensively studied, anion-coordination-driven assembly (ACDA) is just emerging for constructing complex supramolecular structures. Herein two A2nL2n (A = anion, L = ligand; n = 1 or 2) 'aniono'-supramolecular assemblies, i.e. double helicates and the first anion grid, have been constructed based on the coordination between phosphate (PO43-) anion and a bis-tris(urea) ligand. Moreover, the aniono-grid and double helicate motifs can be readily interconverted under ambient conditions by simply changing the counter-cation. These results redefine the power and scope of ACDA, which may represent a new approach in the assembly of well-defined architectures in parallel with the metal coordination-driven assembly of metallo-supramolecules." @default.
- W2945140809 created "2019-05-29" @default.
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- W2945140809 date "2019-01-01" @default.
- W2945140809 modified "2023-10-16" @default.
- W2945140809 title "Construction and interconversion of anion-coordination-based (‘aniono’) grids and double helicates modulated by counter-cations" @default.
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- W2945140809 doi "https://doi.org/10.1039/c9sc02012h" @default.
- W2945140809 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6598520" @default.
- W2945140809 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31341580" @default.
- W2945140809 hasPublicationYear "2019" @default.
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