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- W2945185599 abstract "Herein, a Au-Cu bimetal nanocluster (bi-MNC) with strong emission (13.2% quantum yield) was synthesized and structurally determined. Its structure features a sandwich construction: a ring-like Au7Cu6 kernel is caught in the middle of the two hat-like (CuSPNC)3 motifs with four Br atoms, resulting in a formula of [Au7Cu12(dppy)6(TBBT)6Br4]3+ (dppy = PPh2Py, TBBT = SPh- t-Bu). Interestingly, structural analysis shows that the bonding (N-Cu and μ3S-Cu3) is the key factor to endow this bi-MNC with strong emission by locking the intramolecular motion of surface structure, and destroying the intramolecular π···π interactions is designed to boost emission (19.2% vs 13.2%). Furthermore, the structure-luminescence relationship is further explored by theoretical calculation. This work will provide new idea and strategy to prepare bi-MNCs with strong emission." @default.
- W2945185599 created "2019-05-29" @default.
- W2945185599 creator A5019560977 @default.
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- W2945185599 date "2019-05-16" @default.
- W2945185599 modified "2023-10-15" @default.
- W2945185599 title "The Structure of a Au<sub>7</sub>Cu<sub>12</sub> Bimetal Nanocluster and Its Strong Emission" @default.
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- W2945185599 doi "https://doi.org/10.1021/acs.inorgchem.9b00547" @default.
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