FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2945207310> ?p ?o ?g. }

• W2945207310 endingPage "9929" @default.
• W2945207310 startingPage "9920" @default.
• W2945207310 abstract "Abstract The hydrogenolysis of mono‐ and dinuclear Pd II hydroxides was investigated both experimentally and computationally. It was found that the dinuclear μ‐hydroxide complexes {[(PCN R )Pd] 2 (μ‐OH)}(OTf) (PCN H =1‐[3‐[(di‐ tert ‐butylphosphino)methyl]phenyl]‐1 H ‐pyrazole; PCN Me =1‐[3‐[(di‐ tert ‐butylphosphino)methyl]phenyl]‐5‐methyl‐1 H ‐pyrazole) react with H 2 to form the analogous dinuclear hydride species {[(PCN R )Pd] 2 (μ‐H)}(OTf). The dinuclear μ‐hydride complexes were fully characterized, and are rare examples of structurally characterized unsupported singly bridged μ‐H Pd II dimers. The {[(PCN Me )Pd] 2 (μ‐OH)}(OTf) hydrogenolysis mechanism was investigated through experiments and computations. The hydrogenolysis of the mononuclear complex (PCN H )Pd‐OH resulted in a mixed ligand dinuclear species [(PCN H )Pd](μ‐H)[(PCC)Pd] (PCC=a dianionic version of PCN H bound through phosphorus P, aryl C, and pyrazole C atoms) generated from initial ligand “rollover” C−H activation. Further exposure to H 2 yields the bisphosphine Pd 0 complex Pd[(H)PCN H ] 2 . When the ligand was protected at the pyrazole 5‐position in the (PCN Me )Pd−OH complex, no hydride formed under the same conditions; the reaction proceeded directly to the bisphosphine Pd 0 complex Pd[(H)PCN Me ] 2 . Reaction mechanisms for the hydrogenolysis of the monomeric and dimeric hydroxides are proposed." @default.
• W2945207310 created "2019-05-29" @default.
• W2945207310 creator A5003368942 @default.
• W2945207310 creator A5004130270 @default.
• W2945207310 creator A5004423248 @default.
• W2945207310 creator A5007343230 @default.
• W2945207310 creator A5011374906 @default.
• W2945207310 creator A5042349313 @default.
• W2945207310 creator A5053989261 @default.
• W2945207310 creator A5070272911 @default.
• W2945207310 creator A5070347874 @default.
• W2945207310 creator A5082424242 @default.
• W2945207310 creator A5090193586 @default.
• W2945207310 date "2019-07-03" @default.
• W2945207310 modified "2023-09-25" @default.
• W2945207310 title "Hydrogenolysis of Dinuclear PCN ^R Ligated Pd ^II μ‐Hydroxides and Their Mononuclear Pd ^II Hydroxide Analogues" @default.
• W2945207310 cites W1577362930 @default.
• W2945207310 cites W1899538628 @default.
• W2945207310 cites W1964398054 @default.
• W2945207310 cites W1964913890 @default.
• W2945207310 cites W1968331067 @default.
• W2945207310 cites W1969635440 @default.
• W2945207310 cites W1985549005 @default.
• W2945207310 cites W1990393638 @default.
• W2945207310 cites W1992173555 @default.
• W2945207310 cites W1992687917 @default.
• W2945207310 cites W2004027787 @default.
• W2945207310 cites W2007084913 @default.
• W2945207310 cites W2007170528 @default.
• W2945207310 cites W2008613863 @default.
• W2945207310 cites W2011215428 @default.
• W2945207310 cites W2014479620 @default.
• W2945207310 cites W2015723183 @default.
• W2945207310 cites W2016424453 @default.
• W2945207310 cites W2020561818 @default.
• W2945207310 cites W2023629216 @default.
• W2945207310 cites W2023630158 @default.
• W2945207310 cites W2025270276 @default.
• W2945207310 cites W2040371083 @default.
• W2945207310 cites W2042431246 @default.
• W2945207310 cites W2050646287 @default.
• W2945207310 cites W2053881201 @default.
• W2945207310 cites W2059020082 @default.
• W2945207310 cites W2065128059 @default.
• W2945207310 cites W2065642687 @default.
• W2945207310 cites W2067641534 @default.
• W2945207310 cites W2073285536 @default.
• W2945207310 cites W2081966254 @default.
• W2945207310 cites W2082712943 @default.
• W2945207310 cites W2083648896 @default.
• W2945207310 cites W2085619210 @default.
• W2945207310 cites W2091476329 @default.
• W2945207310 cites W2092816490 @default.
• W2945207310 cites W2110154495 @default.
• W2945207310 cites W2150697053 @default.
• W2945207310 cites W2152247047 @default.
• W2945207310 cites W2315191180 @default.
• W2945207310 cites W2315819438 @default.
• W2945207310 cites W2317412334 @default.
• W2945207310 cites W2319536733 @default.
• W2945207310 cites W2326407293 @default.
• W2945207310 cites W2326764226 @default.
• W2945207310 cites W2329136328 @default.
• W2945207310 cites W2331387246 @default.
• W2945207310 cites W2478972413 @default.
• W2945207310 cites W2484992360 @default.
• W2945207310 cites W2609272021 @default.
• W2945207310 cites W2794398534 @default.
• W2945207310 cites W4247505176 @default.
• W2945207310 cites W4248026240 @default.
• W2945207310 doi "https://doi.org/10.1002/chem.201900507" @default.
• W2945207310 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31090244" @default.
• W2945207310 hasPublicationYear "2019" @default.
• W2945207310 type Work @default.
• W2945207310 sameAs 2945207310 @default.
• W2945207310 citedByCount "5" @default.
• W2945207310 countsByYear W29452073102018 @default.
• W2945207310 countsByYear W29452073102021 @default.
• W2945207310 crossrefType "journal-article" @default.
• W2945207310 hasAuthorship W2945207310A5003368942 @default.
• W2945207310 hasAuthorship W2945207310A5004130270 @default.
• W2945207310 hasAuthorship W2945207310A5004423248 @default.
• W2945207310 hasAuthorship W2945207310A5007343230 @default.
• W2945207310 hasAuthorship W2945207310A5011374906 @default.
• W2945207310 hasAuthorship W2945207310A5042349313 @default.
• W2945207310 hasAuthorship W2945207310A5053989261 @default.
• W2945207310 hasAuthorship W2945207310A5070272911 @default.
• W2945207310 hasAuthorship W2945207310A5070347874 @default.
• W2945207310 hasAuthorship W2945207310A5082424242 @default.
• W2945207310 hasAuthorship W2945207310A5090193586 @default.
• W2945207310 hasConcept C116569031 @default.
• W2945207310 hasConcept C155647269 @default.
• W2945207310 hasConcept C161790260 @default.
• W2945207310 hasConcept C170493617 @default.
• W2945207310 hasConcept C178790620 @default.
• W2945207310 hasConcept C179104552 @default.
• W2945207310 hasConcept C181886296 @default.
• W2945207310 hasConcept C185592680 @default.

• next