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• W2945210330 abstract "The aim of this work is the elaboration of a novel cheap material with high electrocatalytic activity towards methanol electrooxidation. Carbon paste electrode were modified by electropolymerization of poly-(para-phenylenediamine) by cyclic voltammetry during 15 consecutive potential cycles between −0.3 V and 0.9 V vs Ag/AgCl at 50 mVs−1 in 0.1 mol.L-1 HCl solution. The electrodeposition of Nickel particles was then carried out at a constant potentiel of -0.5 V vs Ag/AgCl for 45 s on the polymer film. The composites obtained have been investigated for methanol oxidation, in a concentration range between 0.5 and 4 mol.L-1, the saturation limit reached 3.5 mol.L-1. It appears that the addition of the particles of Nickelsignificantly improves the catalytic activity of the composite with respect to methanol oxidation. Poly-(para-phenylenediamine) and Ni particles have been found to be a promising non-precious electrocatalyst which might be utilized efficiently to enhance the performance of Direct Methanol Fuel Cells." @default.
• W2945210330 created "2019-05-29" @default.
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• W2945210330 date "2019-01-01" @default.
• W2945210330 modified "2023-10-12" @default.
• W2945210330 title "The electrocatalytic oxidation of methanol on a carbon paste electrode modified by poly(para-phenylenediamine) and Nickel particles" @default.
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• W2945210330 doi "https://doi.org/10.1016/j.matpr.2019.04.033" @default.
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