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• W2945233208 abstract "Several pseudohalide containing ionic liquids with quarternary ammonium counter cations of the general formula [ R 3 MeN]X [ R = ethyl ( 1X ), n ‐butyl ( 2X ) with X – = CN – , N 3 – , OCN – , and SCN – ] were synthesized by decomposition of the corresponding trialkylammonium methylcarbonate in the reaction with Me 3 Si– X . We also treated 2CN with OP(OMe) 3 , yielding [ n Bu 3 MeN][O 2 P(OMe) 2 ] and acetonitrile (Me‐CN). The double salt [ n Bu 3 MeN] 2 {[B(OMe) 3 (CN)](CN)} was obtained from the reaction of 2CN with B(OMe) 3 , featuring the formation of the monocyanotrimethoxyborate anion, [B(OMe) 3 (CN)] – , co‐crystallized with [ n Bu 3 MeN]CN. [ n Bu 3 MeN] 2 {[B(OMe) 3 (CN)](CN)} was fully characterized including structure elucidation." @default.
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• W2945233208 date "2019-05-16" @default.
• W2945233208 modified "2023-10-16" @default.
• W2945233208 title "Pseudo Halide Chemistry in Ionic Liquids with Decomposable Anions" @default.
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• W2945233208 doi "https://doi.org/10.1002/zaac.201900055" @default.
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