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• W2945313461 abstract "Chiral resolution using non-functionalized mesoporous particles is demonstrated for a variety of enantiomeric pairs. This is achieved through the use of supramolecular templated silica materials prepared with guanosine monophosphate (NGM-1) and folic acid (NFM-1) which enable direct chiral transcription onto the surface of the mesopores after solvent extraction and post calcination of the template. The chiral selectivity and kinetics of the mesoporous materials are measured by circular dichroism (CD) spectroscopy on adsorbed molecules with different affinities for the pore surface. NGM-1 and NFM-1 have opposite enantiomeric selectivity for enantiomeric pairs. These results significantly increase the potential of mesoporous materials for chiral separation and enantiomeric catalysis." @default.
• W2945313461 created "2019-05-29" @default.
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• W2945313461 date "2019-06-28" @default.
• W2945313461 modified "2023-10-15" @default.
• W2945313461 title "Chiral Resolution using Supramolecular‐Templated Mesostructured Materials" @default.
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• W2945313461 doi "https://doi.org/10.1002/anie.201900950" @default.
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