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• W2945334575 abstract "π-Conjugated azobenzene derivatives were reported to couple azo moieties with aryl fluorophore. Using the photochemistry of the C2-bridged azobenzene, we have accomplished two diazocine-based photoswitching molecules (cAz1 and cAz2). In addition to remarkable photochromic properties, they show a turn-on fluorescence, and the emission was highly enhanced with quantum efficiency increasing up to 0.22 for cAz1. The emission remains persistent and can only be switched off via thermal deactivation. They display greater optical responses, compared with the linear analogues (Az1-Az4). This work may provide a new scaffold toward advanced light-emitting materials using photoswitchable systems." @default.
• W2945334575 created "2019-05-29" @default.
• W2945334575 creator A5021860957 @default.
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• W2945334575 date "2019-05-14" @default.
• W2945334575 modified "2023-10-17" @default.
• W2945334575 title "Diazocine Derivatives: A Family of Azobenzenes for Photochromism with Highly Enhanced Turn-On Fluorescence" @default.
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• W2945334575 doi "https://doi.org/10.1021/acs.orglett.9b01215" @default.
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