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- W2945353563 abstract "An electrochemiluminescence (ECL) switch sensor with a dual-recognition mechanism was developed based on complexation reactions and a molecular imprinted film (MIP). The MIP was prepared on a gold electrode with ferroferric oxide/carbon quantum dots (Fe3O4/C-dots) via electrochemical polymerization. An L-canavanine–trinitrobenzene complex was used as the template molecule and o-phenylenediamine was used as the functional monomer. Further, C-dots were used as the ECL signal elements and the L-canavanine–trinitrobenzene complex could quench the ECL signal. Subsequently, by using the elution and re-adsorption of the template molecule as the control switch, it was possible to control the ECL intensity of the sensor, and establish a new method for rapidly measuring L-canavanine. A sensor that combined complexation recognition and imprinting recognition demonstrated excellent performance in terms of recognizing specific target molecules. The detection limits of this method reached 7.32 × 10−11 mol L−1, and the measurement results for practical samples were satisfactory." @default.
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- W2945353563 date "2019-07-01" @default.
- W2945353563 modified "2023-10-17" @default.
- W2945353563 title "Highly selective molecular imprinting electrochemiluminescence switch sensor for biotoxin L-canavanine measurement" @default.
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- W2945353563 doi "https://doi.org/10.1016/j.microc.2019.05.025" @default.
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