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- W2945403003 abstract "A new, direct and chemoselective esterification of α-hydroxyacids was developed using a reversible covalent-binding strategy. Kinetic studies of the transesterification of methyl acetate with ethanol to form ethyl acetate catalysed by an ionic liquid (IL), 4-(3-methyl-1-imidazolio)-1-butanesulfonic acid triflate [HO3S-bmim] CF3SO3 were reported. Biodiesel, a mixture of fatty acid methyl esters, is manufactured by transesterification of natural glycerides by MeOH. Potential energy surfaces for nucleophilic displacements at phosphorus in dimethyl methyl-, chloromethyl-, dichloromethyl-, and trichloromethyl-phosphonates were computed by density functional theory (DFT) methods. The spontaneous hydrolysis of 2-pyridyl phosphate (PP) is a good model for the special mechanism for the hydrolysis of phosphate monoester monoanions (M-), which are believed to react via an initial proton transfer equilibrium to form the highly reactive species (M+=), the proton transfer occurring from a hydroxyl group attached to phosphorus to the oxygen of the OR group." @default.
- W2945403003 created "2019-05-29" @default.
- W2945403003 creator A5075648833 @default.
- W2945403003 date "2016-10-07" @default.
- W2945403003 modified "2023-10-16" @default.
- W2945403003 title "Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and Their Derivatives" @default.
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- W2945403003 doi "https://doi.org/10.1002/9781118707838.ch2" @default.
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