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• W2945459311 startingPage "130336" @default.
• W2945459311 abstract "Functionalized 1,2-oxazinanes are interesting and valuable heterocycles with potential applications in synthetic and medicinal chemistry. A straightforward strategy for quick access to unprecedented trans-4-hydroxyl-5-azido/cyano/amino 1,2-oxazinanes are developed: N-COR 3,6-dihydro- 1,2-oxazine oxides are prepared with ease from related dihydro- 1,2-oxazines and opened by nucleophiles TMSN3, TMSCN and aryl/alkyl amines. Appropriate Lewis acid catalysts are found playing a vital role for both reaction rate and regioselectivity. The N-COR group can be removed under mild conditions to provide highly desirable NH 1,2-oxazinanes inaccessible via previous methods." @default.
• W2945459311 created "2019-05-29" @default.
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• W2945459311 date "2019-11-01" @default.
• W2945459311 modified "2023-10-18" @default.
• W2945459311 title "Straightforward synthesis of 4,5-bifunctionalized 1,2-oxazinanes via Lewis acid promoted regio- and stereo-selective nucleophilic ring-opening of 3,6-dihydro-1,2-oxazine oxides" @default.
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• W2945459311 doi "https://doi.org/10.1016/j.tet.2019.05.015" @default.
• W2945459311 hasPublicationYear "2019" @default.
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