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- W2945571729 abstract "Polymers with a lower critical point solution temperature (LCST) are widely investigated responsive materials and are already in use for smart materials applications, e.g., for medicinal purposes. Hydrogels prepared from these polymers usually exhibit a shrinking behavior over a broad temperature range, rather than an expected sharp phase transition. One reason for this is their cloud point temperature (Tcp) dependence on the concentration in water. Here, we investigate this behavior on the example of copolymers prepared by copolymerization of 2-ethyl-2-oxazoline (EtOx) with the respective heptyl (HepOx), butyl (BuOx), and isopropyl (iPrOx) derivatives, respectively. The resulting copolymers show greatly different dependencies of their TCP on concentration. While P(EtOx-stat-HepOx)s show a strong linear increase of Tcp on polymer concentration, the Tcp of P(EtOx-stat-BuOx)s is only slightly raising at higher concentration. P(EtOx-stat-iPrOx)s have two plateau regions in their water/polymer phase diagram. In general, copolymers with less strong differences in their hydrophobicity might be best suited for discretely thermo-switchable hydrogels, because they show the lowest dependence of Tcp on polymer concentration." @default.
- W2945571729 created "2019-05-29" @default.
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- W2945571729 date "2019-06-01" @default.
- W2945571729 modified "2023-10-16" @default.
- W2945571729 title "Investigations on the thermoresponsive behavior of copoly(2-oxazoline)s in water" @default.
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- W2945571729 cites W1971573959 @default.
- W2945571729 cites W1973724964 @default.
- W2945571729 cites W1974777844 @default.
- W2945571729 cites W1981852256 @default.
- W2945571729 cites W1982218431 @default.
- W2945571729 cites W1983836584 @default.
- W2945571729 cites W1984215364 @default.
- W2945571729 cites W1985964507 @default.
- W2945571729 cites W1988031042 @default.
- W2945571729 cites W1993981910 @default.
- W2945571729 cites W2006631374 @default.
- W2945571729 cites W2011299523 @default.
- W2945571729 cites W2011735376 @default.
- W2945571729 cites W2013053325 @default.
- W2945571729 cites W2017529781 @default.
- W2945571729 cites W2021136164 @default.
- W2945571729 cites W2022221214 @default.
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- W2945571729 cites W2032356822 @default.
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- W2945571729 cites W2036725443 @default.
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- W2945571729 cites W2312624262 @default.
- W2945571729 cites W2317978718 @default.
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- W2945571729 cites W2474921903 @default.
- W2945571729 cites W2507195106 @default.
- W2945571729 cites W2524287034 @default.
- W2945571729 cites W2606162141 @default.
- W2945571729 cites W2750166441 @default.
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- W2945571729 doi "https://doi.org/10.1016/j.polymer.2019.05.040" @default.
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