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• W2945603903 startingPage "4174" @default.
• W2945603903 abstract "Organic sulfur compounds have broad applications in biology, medicine and material sciences and intensive efforts have been devoted to developing mild and general C–S bond-forming methods. However, a mild, transition-metal-free, direct C–H bond functionalization method remains elusive. Here, we report the use of an internal oxidant-directing strategy to achieve this goal. The cascade reactions described here show excellent chemoselectivity and a wide substrate scope for both oxyamines and sulfenylation reagents. This study enlarges the synthesis toolbox for preparing structurally diverse sulfilimines under mild conditions." @default.
• W2945603903 created "2019-05-29" @default.
• W2945603903 creator A5024848520 @default.
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• W2945603903 date "2019-08-01" @default.
• W2945603903 modified "2023-10-15" @default.
• W2945603903 title "An internal oxidant-directing strategy enabling transition metal-free C–S bond ligation" @default.
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• W2945603903 doi "https://doi.org/10.1016/j.tet.2019.05.021" @default.
• W2945603903 hasPublicationYear "2019" @default.
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