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- W2945752173 abstract "A zinc-/quinine-mediated enantioselective Aldol-type reaction of trifluorodiazoethane (CF3CHN2) with various aldehydes is described. This study demonstrated the feasibility of utilizing CF3CHN2 as an effective hard nucleophile in catalytic asymmetric transformations. Furthermore, the synthetic utility of this protocol is exemplified by the construction of a diverse set of chiral β-trifluoromethylated alcohols, including a valuable HDAC inhibitor precursor." @default.
- W2945752173 created "2019-05-29" @default.
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- W2945752173 date "2019-05-24" @default.
- W2945752173 modified "2023-10-06" @default.
- W2945752173 title "Construction of Chiral β-Trifluoromethyl Alcohols Enabled by Catalytic Enantioselective Aldol-Type Reaction of CF<sub>3</sub>CHN<sub>2</sub>" @default.
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- W2945752173 doi "https://doi.org/10.1021/acs.orglett.9b01468" @default.
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