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- W2945792947 abstract "The production of fuels from biomass is a key factor for sustainability. With this aim, we have studied the conversion of d-Glucose into short-chain alkanes in a one-pot biphasic catalytic system, evaluating different modifications of Ru/MCM-48: Ru/Al-MCM-48 and Ru/MCM-48 with the addition of tungstophosphoric acid, and compared with a commercial Ru/C. Additionally, different combinations of the previous were studied. Catalysts were characterized in terms of X-ray Diffraction/Small Angle X-Ray Scattering, N2 adsorption/desorption, Temperature Programmed Reduction with H2, Temperature Programmed Desorption of Ammonia, Transmission Electron Microscopy and Atomic Absorption. The reaction was carried out at 190 °C under 5 MPa of H2 in a biphasic n-decane–water system. In the absence of tungstophosphoric acid, the reaction took place through a first hydrogenation to sorbitol followed by dehydration and hydrodeoxigenation. In this terms, the presence of Al-MCM-48 showed to play a very important role in the production of light alkanes, favoring the dehydration step. The reverse trend was observed in the presence of tungstophosphoric acid. In this case, the reaction occurred first by the dehydration of glucose, followed by hydrogenation and hydrodeoxigenation. Here, once the dehydration had been promoted by tungstophosphoric acid, the following hydrogenation step was favored on Ru/C, which is preferentially located in the organic phase. The global results, in terms of alkane formation, shows how the presence of Al-MCM-48 conducts to promising results, outperforming commercial or other literature reported systems." @default.
- W2945792947 created "2019-05-29" @default.
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- W2945792947 date "2019-09-01" @default.
- W2945792947 modified "2023-10-18" @default.
- W2945792947 title "Improving conversion of d-Glucose into short-chain alkanes over Ru/MCM-48 based catalysts" @default.
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- W2945792947 doi "https://doi.org/10.1016/j.micromeso.2019.05.035" @default.
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